catena-Poly[[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ2-iodido]
نویسندگان
چکیده
The solvothermal reaction of copper(I) iodide and 1,10-phenanthroline (phen) in ethanol yielded the title polymeric compound, [CuI(C(12)H(8)N(2))](n). The asymmmetric unit comprises one Cu(+) cation, one I(-) anion and one phen ligand. Each Cu(+) cation is in a distorted tetrahedral coordination by two iodide anions and two N atoms from a bidentate chelating phen ligand. The Cu(+) cations are bridged through the iodide anions, leading to a zigzag chain structure extending parallel to [100]. There are π-π inter-actions among adjacent phen ligands of one chain [centroid-centroid distance = 3.693 (3) Å].
منابع مشابه
catena-Poly[[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ-thiocyanato-κ2 N:S-[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ-cyanido-κ2 N:C]
In the title complex, [Cu(2)(CN)(NCS)(C(12)H(8)N(2))(2)], which was synthesized under hydro-thermal conditions, both Cu(I) atoms have a slightly distorted tetra-hedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thio-cyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu-CN-Cu-SCN}(n) chains are formed along...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ-thiocyanato-κ2 N:S]
In the title complex, [Cu(NCS)(C(12)H(8)N(2))](n), the Cu(I) ion is in a distorted tetra-hedral CuN(3)S coordination geometry. The thio-cyanate ligand acts as bridging ligand, forming chains along [100]. A crystallographic mirror plane runs through the Cu(I) ion, the thio-cyanate ligand and the middle of the phenanthroline ligand.
متن کاملA second polymorph of catena-poly[[(1,10-phenanthroline-κ2 N,N′)copper(II)]-di-μ-thiocyanato-κ2 N:S;κ2 S:N]
In the title coordination polymer, [Cu(NCS)(2)(C(12)H(8)N(2))](n), the Cu(II) atom is situated on a twofold rotation axis and is coordinated by two N atoms from the bidentate 1,10-phenanthroline ligand and four thio-cyanate groups to confer a CuN(4)S(2) octa-hedral geometry and resulting in a layer structure extending parallel to (100).
متن کاملIodido(1,10-phenanthroline-κ2 N,N′)(piperine-1-carbodithioato-κ2 S,S′)copper(II)
In the title compound, [Cu(C(6)H(10)NS(2))I(C(12)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the phenanthroline ligand and two S atoms from the piperidyl-dithio-carbamate ligand in a distorted square-pyramidal environment.
متن کاملcatena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2 N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2 O 2:O 5]
The polymeric title compound, [Cu(C(6)H(2)O(5))(C(12)H(8)N(2))(C(5)H(10)N(2)O)](n), is composed of an infinite chain formed along [100] by linking the (1,3-dimethyl-imidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxyl-ate groups of the furan-2,5-dicarboxyl-ate ligand. The Cu(II) atom, which lies on a twofold rotation axis, displays a square-pyramidal coordinat...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010